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SEDIMENTATION EXPERIMENT, Study notes of Particle Physics

LABORATORY MANUAL WITH CONCLUSION

Typology: Study notes

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ChE 536L – Chemical Laboratory 1
Experiment No. 7
Sedimentation
INTRODUCTION
Sedimentation is the process of deposition of solid material from a fluid, usually air
or water, from a state of suspension. It is widely observed in nature in the formation of rocks
and ore deposits. One important branch of Geology, Sedimentology or Sedimentary
Petrology, studies the origin of rocks by this method. Sedimentation has also a great scientific
and industrial importance, especially in the mining and chemical industry. (Bustos, 1999)
The size and type of particles to be removed have a significant effect on the operation
of the sedimentation tank. Sand or silt can be removed very easily because of their density.
The velocity of the water-flow channel can be slowed to less than one foot per second and
most of the sand and silt will be removed by simple gravitational forces. In contrast, colloidal
material (small particles that stay in suspension and make the water seem cloudy) will not
settle until the material is coagulated and flocculated by adding a chemical, such as iron salt
or aluminum sulfate. The shape of the particle also affects its settling characteristics. A round
particle, for example, will settle much more readily than a particle that has ragged or irregular
edges. All particles also tend to have a slight electrical charge. Particles with the same charge
tend to repel each other. This repelling action keeps the particles from congregating into flocs
and settling (Kocamemi, n.d.).
APPARATUS/MATERIALS
Cornstarch
Water
Batch/Sedimentation Apparatus
Stirring Rod
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ChE 536L – Chemical Laboratory 1 Experiment No. 7 Sedimentation INTRODUCTION Sedimentation is the process of deposition of solid material from a fluid, usually air or water, from a state of suspension. It is widely observed in nature in the formation of rocks and ore deposits. One important branch of Geology, Sedimentology or Sedimentary Petrology, studies the origin of rocks by this method. Sedimentation has also a great scientific and industrial importance, especially in the mining and chemical industry. (Bustos, 1999) The size and type of particles to be removed have a significant effect on the operation of the sedimentation tank. Sand or silt can be removed very easily because of their density. The velocity of the water-flow channel can be slowed to less than one foot per second and most of the sand and silt will be removed by simple gravitational forces. In contrast, colloidal material (small particles that stay in suspension and make the water seem cloudy) will not settle until the material is coagulated and flocculated by adding a chemical, such as iron salt or aluminum sulfate. The shape of the particle also affects its settling characteristics. A round particle, for example, will settle much more readily than a particle that has ragged or irregular edges. All particles also tend to have a slight electrical charge. Particles with the same charge tend to repel each other. This repelling action keeps the particles from congregating into flocs and settling (Kocamemi, n.d.).

APPARATUS/MATERIALS Cornstarch Water Batch/Sedimentation Apparatus Stirring Rod

1000 mL Beaker

PROCEDURE

  1. Prepare a desired amount of 2.5%, 5%, 7.5% and 10% concentration by weight suspension of powder in water.
  2. Take note of the readings of the interface at convenient timed intervals. Record also the rise of sludge interface at the base of the cylinder.
  3. Allow a period of 24 hours to elapse for the final compaction readings Hence, height of the port is being measured. Suspension or the mixture of cornstarch and water prepared is to be tested and placed in the column. The suspension is being mixed completely to ensure uniform distribution of particles. At time interval, a portion of the sample is removed from the port and carried out in order to determine the initial concentration. The suspension is allowed to settle in four different height. Intermittent samples are removed at appropriate time intervals (Kocamemi, n.d.).

OBSERVATION/ RESULTS: Table. 1 Height of slurry and interface with respect to time

Sample 1 Sample 2 Sample 3 Sample 4 Z (^) i (m) 4.85 4.8 4.65 4. (s) ZL (m) 300 0.1 0.2 0.05 0. 600 0.11 0.22 0.06 0. 1200 0.15 0.325 0.13 0.

MODEL CALCULATION

v= where: v= rate-limiting zone/velocity (m/s) Zi= height of slurry initially (m) ZL = height of the interface (m) = time to reach interface (s) A=2πrh where: r= 0.0254 m RESULTS & DISCUSSION At a short period of two minutes time interval, particles are well distributed in a water phase at its flocculated suspension initial state based on the nature of the CaCO3 particles suspended in water. In the medium time period of about 8 mins, clear supernatant above the surface is seen while remains cloudy in the middle interface and there is a cake formation at the bottom. One factor affecting sedimentation is the particle size diameter. The formed flocs will cause an increase in sedimentation rate due to increase in size of sedimenting particles. It does not only depend on size but also on porosity, preserve in the sediment which contains an amount of entrapped liquid. Thus, the final volume of sediment is relatively large. CONCLUSION Sedimentation is another solid-liquid separation technique used in wastewater treatment to remove the largest particles in the wastewater. In this experiment, a

sedimentation apparatus was utilized in executing batch sedimentation of suspensions of different concentration. Suspensions A and B had different concentrations and it was known that at higher concentration, settling time became longer which means that the sedimentation rate was lower to this condition. Suspensions B and C had the same concentration but they had dissimilar initial suspension heights. Even though they had different initial heights, the sedimentation rate was unaffected generating almost the same settling velocity curve. Finally, adding coagulant made the sedimentation rate became faster since this substance made the particles larger, resulting to settle faster. Through the experiment, the settling velocity curves of the various suspensions were analyzed to determine the effect of the initial concentration, initial height suspension and addition of coagulant to the rate of sedimentation. It could be observed that in every initial height of four different concentration with respect to time, velocities and area varies. By the influence of the force of gravity, the unstable and destabilized suspended solids are being separated. Therefore, in dilute suspensions their concentrations of particles is not sufficient to cause significant displacement of water as they settle or in which the particles will not be close enough for velocity field interference to occur.

REFERENCE Bustos, M.C. (1999, September 30) Sedimentation and Thickening: Phenomenological Foundation and Mathematical Theory. Retrieved from https:// books.google.com.ph/books? id=im3zGTTwVa4C&pg=PA1&dq=sedimentation&hl=en&sa=X&ved=0ahUKEwiw2Yuxje_ gAhXYdN4KHcdUBC4Q6AEITDAH#v=onepage&q=sedimentation&f=false Lamanilao, J., (2010, June 4) Sedimentation: ChELab Final Report. Retrieved from https://www.slideshare.net/jeufier/sedimentation-finalrepz