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Lecture Notes on Functional Groups, Lecture notes of Organic Chemistry

Structural Formulas and chemical reactions, Naming organic compounds.

Typology: Lecture notes

2020/2021

Uploaded on 05/24/2021

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kavinsky 🇺🇸

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Functional Groups
functional group: an atom, or group of atoms (with specific connectivity), exhibiting
identical chemical reactivity regardless of the molecule containing it; the reactivity of
individual functional groups dictates the reactivity of the molecule of which they are a
part
divide organic compounds into classes
sites of characteristic chemical reactions
serve as basis for naming organic compounds
A. Alkanes
contain only carbon-carbon and carbon-hydrogen single bonds
B. Alkenes
contain a carbon-carbon double bond
C. Alkynes
contain a carbon-carbon triple bond
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Functional Groups

functional group : an atom, or group of atoms (with specific connectivity), exhibiting identical chemical reactivity regardless of the molecule containing it; the reactivity of individual functional groups dictates the reactivity of the molecule of which they are a part

  • divide organic compounds into classes
  • sites of characteristic chemical reactions
  • serve as basis for naming organic compounds

A. Alkanes

  • contain only carbon-carbon and carbon-hydrogen single bonds

B. Alkenes

  • contain a carbon-carbon double bond

C. Alkynes

  • contain a carbon-carbon triple bond

D. Arenes

  • contain a benzene group

E. Alcohols

  • contain an –OH (“hydroxyl”) group bonded to a tetrahedral carbon atom

F. Ethers

  • contain an oxygen atom bonded to two carbon atom groups by single bonds

J. Carboxylic Amides (Amides)

  • contain an “amide” group – a carboxylic acid (-COOH) group where the -OH group is replaced with an amine

K. Carboxylic Esters (Esters)

  • contain an “ester” group – a carboxylic acid (-COOH) group where the H atom is replaced with a carbon containing group

L. Carboxylic Anhydrides (Anhydrides)

  • contain an “anhydride” group – an oxygen atom bonded to two C=O (“carbonyl”) groups

M. Nitriles

  • contain a “cyano” group (C≡N) bonded to a carbon atom group (i.e., at the carbon atom of the cyano group)